Refrigeration/Freezing of Flammable Liquids

(Printable version)

Flammable liquids must never be stored in standard domestic refrigerators, freezers, or cold rooms

  • Vapors from the stored chemicals can accumulate over time and come in contact with an electrical spark, thus creating a powerful explosion
    • Sparks can occur with normal operations of these appliances such as when a thermostat, defrost timer, internal lighting unit, or the motor turns on and off
  • Even a small quantity of flammable liquid stored in a non-approved refrigerator or freezer can cause a large explosion
  • Explosions, injuries, and costly laboratory fires have resulted from storing flammable liquids in domestic refrigerators or freezers

Image of refrigerator explosion aftermath

 

University of Vermont: Flammable liquids stored in a refrigerator resulted in an explosion

Aftermath of flammable vapor explosion

 

University of Virginia: A thermostat spark ignited flammable vapors

 

Flammable material refrigerators and explosion-proof refrigerators are designed to prevent ignition of flammable vapors and can be used for storage of flammable liquids

  • A flammable liquid is defined by OSHA 1910.1200 App B Physical Criteria as having a flash point of not more than 93 °C (199.4 °F).
    • Review the Safety Data Sheet (SDS) for the flash point of liquids
  • Flammable-safe refrigerators will be U.L. listed, and bear a label stating "FLAMMABLE STORAGE - KEEP FIRE AWAY"
  • Explosion-proof refrigerators are constructed so that there are no sparks or static charges generated either inside or outside of the unit
    • These refrigerators are typically used in specialized locations such as solvent dispensing rooms
  • Avoid storing flammable liquids with strong oxidizers or acids and provide suitable secondary containment
  • Chill flammable liquids in an ice bucket prior to use rather than storing them in a standard domestic refrigerator

 

COMMON LABORATORY SOLVENTS

Do not store these flammable liquids in standard domestic refrigerators

Chemical Flash Point (°F) Chemical Flash Point (°F)
Acetone 4 Isopropanol 53
Acetonitrile 42 Methanol 54
Benzene 12.2 Petroleum Ether 20
Butanol 84 Propyl Alcohol 74
Cyclohexene 10 Pyridine 68
Dioxane 54 Tetrahydrofuran 6
Ethyl Acetate 24 Tetramethylethylenediamine 50
Ethyl Alcohol 55 Toluene 40
Ethyl Alcohol (20%) 97 Triethylamine 20
Ethyl Ether -49 Xylene 84
Hexane -7 2-Methylbutane -60

 

Additional Incidents Involving Flammable Liquid Storage or Use in Non-Flammable Refrigerators/Freezers